| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Maimuna Kibenga Tarishi | Permanent Representative | 2019 - 2023 |
| 2 | H.E. James A. Msekela | Permanent Representative | 2017 - 2019 |
| 3 | H.E. Modest Jonathan Mero | Permanent Representative | 2013 - 2016 |
| 4 | H.E. Dr. Marten Lumbanga | Permanent Representative | 2006 - 2012 |
| 5 | H.E. Charles K. Mutalemwa | Permanent Representative | 2002 - 2006 |
| 6 | H.E. Ali S. Mchumo | Permanent Representative | 2000 - 2006 |
| 7 | H.E. Eli E. Mtango | Permanent Representative | 1993 - 1995 |
| 8 | H.E. Amir H. Jamal | Permanent Representative | 1985 - 1992 |
| 9 | H.E. Dr. Wilbert K. Chagula | Permanent Representative | 1979 - 1985 |
